Product ID:E-Z STEAM DISTILLED TURPENTINE
MSDS Date:07/03/1987
FSC:8010
NIIN:00N033350
MSDS Number: BPLZD

E E ZIMMERMAN COMPANY

PITTSBURGH, PA 15238
US

Emergency Phone: 412-963-0949

Info Phone: 412-963-0949

Cage: ZMMER

E E ZIMMERMAN CO

111254 PITTSBURGH, PA 15238 US

Telephone: 412-963-0949

Cage: ZMMER

APPLICABLE AIR POLLUTION CONTROL REGULATIONS.

RTECS: 9999999ZZ

TURPENTINE

CAS: 8006-64-2

RTECS: YO8400000

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

1,100 PPM FOR 3.5-4 HRS CAUSES EYE IRRIT, HDCH,

RTECS: 9999999ZZ

MODERATE,

RTECS: 9999999ZZ

HYDROCARBON SOLV. ASPIR INTO LUNGS COULD

RTECS: 9999999ZZ

AIR, AS SPONT HEATING MAY OCCUR. PROT MEASURES

RTECS: 9999999ZZ

ISOLATE & THORO CLEAN ALL EQUIP, PIPING/VESSELS

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT)1,400-5,200 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:WARNING! MAY CAUSE EYE, SKIN & RESP
TRACT IRRIT. VAPS MAY CAUSE DROWS & DIZZ. IF SWALLOWED, VOMIT MAY
CAUSE FATAL LUNG DMG. EYES:LIQ & VAPS - MAY CAUSE IRRIT.
SKIN:CAUSES DEFAT WHICH CAN LEAD TO IRRIT & DERM. INHAL:VAPS MAY
CAUSE CNS DEPRESS & MUC MEMB IRRIT. SYMPS OF OVEREXP ARE LT HEAD
(DIZZ), HDCH, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INTOX WHICH COULD LEAD TO UNCON. VAPS
MAY ALSO CAUSE IRRIT OF UPPER RESP TRACT. INGEST:MAY CAUSE STOM
PAIN, NAUS & VOMIT, IRRIT OF MOUTH & THROAT. ASPIR INTO LUNGS AFTER
INGEST WILL CAUSE SEV LUNG DMG (PULM EDEMA & HEMORR) WHICH COULD
BE FATAL. ACUTE:SUFFICIENT DOCUMENTED INCIDENTS OF FATAL POIS HAVE
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE KNOWN

First Aid:EYE:IMMED FLUSH W/PLENTY OF LOW PRESS H*2O FOR @ LST 15 MINS.
REMOVE ANY CONTACT LENSES TO ENSURE THORO FLUSHING. CALL MD.
SKIN:PROMPTLY FLUSH W/RUNNING H*2O. REMOVE CONTAM CLTHG. WASH CLTHG
BEFORE RE USE. INHAL:REMOVE TO FRESH AIR. IF BRTHG HAS STOPPED,
GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE O*2. CALL MD. INGEST:DO NOT
INDUCE VOMIT. CALL MD. GET IMMED MED ATTN. NOTE TO MD:MATL CONTAINS
(ING 4)

Flash Point Method:TCC
Flash Point:91.4F,33.0C
Lower Limits:0.8%
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM, CO*2 OR HALON.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . COOL CONTAINERS W/WATER IF EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:REMOVE SOURCE OF IGNITION. SMALL SPILLS:ADD
INERT ABSORBENT, SWEEP UP & PLACE MATERIAL IN METAL DRUMS FOR
DISPOSAL. LARGE SPILLS:DIKE TO CONTAIN & PUMP INTO DRUMS FOR USE OR
DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONT W/EYES, SKIN & CLTHG. AVOID
BRTHG VAPS. DO NOT SWALLOW. KEEP AWAY FROM HEAT, SPARKS & OPEN
FLAME.
Other Precautions:PROD MAY REACT W/ACIDS, AL CHLORIDE/BORON TRIFLUORIDE
& SHLD NOT BE STORED NEAR SUCH MATLS. ELIM IGNIT SOURCES & PVNT
BUILDUP OF STATIC ELEC CHARGES. DISCARD PROPERLY SUCH ITEMS AS
RAGS, INSULATION & TRASH SOAKED W/MATL & EXPOSED TO (ING 5)

Respiratory Protection:APPROPRIATE NIOSH/MSHA APPRVD RESP PROT IS REQD
WHEN EXPOS TO AIRBORNE CONTAMINANT IS LIKELY TO EXCEED ACCEPTABLE
LIMITS. NIOSH/MSHA APPRVD RESPS SHOULD BE SELECTED & USED I/A/W
OSHA, SUBPART I (29CFR 1910.134) & MFR'S RECOMS.
Ventilation:ADEQ VENT SHLD BE PROVIDED TO KEEP VAPS CONCS BELOW ACCEPT
EXPOS LIMS. DISCHARGE FROM VENT SYS SHLD COMPLY W/ (ING 7)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:APPROP PROT CLTHG. EYEWASH FOUNTAINS &
SAFETY SHOWERS SHOULD BE EASILY ACCESSIBLE.
Work Hygienic Practices:WASH THORO AFTER HNDLG & BEFORE EATING,
DRINKING/SMOKING. REMOVE CONTAM CLTHG PROMPTLY & CLEAN THORO BEFORE
REUSE.
Supplemental Safety and Health
CNDTNS (STAB):SOAKED W/MATL & EXPOSED TO AIR. EFTS OF OVEREXP:OCCURRED
TO ALLOW CALCULATION OF LD BTWN 1,100 & 2,400 MG/KG/APPROX 4-6 OZ
FOR ADULT. COUGHING & CHOKING OFTEN OCCUR AFTER INGEST. ASPIR M AY
LEAD TO PULM EDEMA & PNEUM. ACCIDENTAL EYE CONT LEADS TO SEV PAIN
W/REVERSIBLE CORNEAL INJURY. SUBACUTE:720 - (ING 2)

Boiling Pt:B.P. Text:>313F,>156C
Vapor Pres:4 @ 20C
Vapor Density:HVR/AIR
Spec Gravity:0.86
Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID; TYPICAL PINE ODOR.
Percent Volatiles by Volume:99

Stability Indicator/Materials to Avoid:YES
ACIDS, ALUMINUM CHLORIDE, BORON TRIFLUORIDE.
Stability Condition to Avoid:SUSCEPTIBLE TO OXIDATION & SELF-HEATING.
SPONT HEATING MAY OCCUR IN SUCH ITEMS AS MOPS, RAGS, INSULATION &
TRASH(SUPDAT)
Hazardous Decomposition Products:PRODS OF COMBUST:CO, CO*2 & SMOKE.
DEPENDING ON CNDTNS, SOME ALIPHATIC ALDEHYDES & CARBOXYLIC ACIDS
ALSO MAY BE FORMED.

Waste Disposal Methods:INCINERATION I/A/W LOCAL, STATE & FEDERAL
REGULATIONS. THIS PRODUCT EXHIBITS CHARACTERISTIC OF IGNITABILITY
AS DEFINED IN HAZARDOUS WASTE REGS 40CFR261, SUBPART C. THEREFORE,
DISPOSAL OF UNUSED PRODUC T MUST COMPLY W/HAZARDOUS WASTE REGS.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.